Bis(2,2′-bipyridyl-κ2 N,N′)dichloridorhodium(III) perchlorate
نویسندگان
چکیده
The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa-hedral environment. The Cl ligands are cis. Two intramolecular C-H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, mol-ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).
منابع مشابه
cis-Bis(2,2′-bipyridine-κ2 N,N′)dichloridoiron(III) perchlorate
In the crystal structure of the title compound, [FeCl(2)(C(10)H(8)N(2))(2)]ClO(4), the coordination around the Fe(III) atom is approximately octa-hedral. The equatorial positions are occupied by two N atoms from two 2,2'-bipyridyl ligands [Fe-N = 2.121 (5) and 2.147 (5) Å] and two Cl atoms [Fe-Cl = 2.220 (2) and 2.2074 (18) Å]. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and C-H⋯π inte...
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The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H⋯Br and O-H⋯O hydrogen bonds, generating a one-dimensional chain.
متن کاملBis(2,2′-bipyridine-κ2 N,N′)(thiocyanato-κN)copper(II) perchlorate
The asymmetric unit of title compound, [Cu(NCS)(C(10)H(8)N(2))(2)]ClO(4), contains a bis-(2,2'-bipyridine)(isothio-cyanato)copper(II) cation and a perchlorate anion. In the cation, the Cu(2+) ion is coordinated by four N atoms from two bidentate 2,2'-bipyridine mol-ecules and an N atom from an isothio-cyanate anion, resulting in a distorted CuN(5) pyramidal configuration. The crystal structure ...
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In the title complex, [Cd(C(6)H(4)N(3)O(3)S)(2)(C(10)H(8)N(2))], the Cd(2+) cation is located on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related benzotriazole-4-sulfonate anions and two N atoms from a 2,2-bipyridyl ligand, displaying a distorted CdN(4)O(2) octa-hedral geometry. The crystal structure is stabilized by N-H⋯O and C-H⋯O hydrogen-bonding ...
متن کاملBis(2,2′-bipyridyl-κ2 N,N′)(nitrato-κ2 O,O′)(trifluoroacetato-κO)cadmium(II)
In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta-coordinated by two chelating 2,2'-bipyridyl ligands [Cd⋯N 2.370 (6)-2.416 (6) Å], one carboxyl-ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro-acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoro-methyl fragment is rotationally disordered between two ...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012